4-Bromo-2-[(E)-(4-fluorophenyl)iminomethyl]phenol
نویسندگان
چکیده
In the title compound, C(13)H(9)BrFNO, the dihedral angle between the substituted benzene rings is 9.00 (11)°. Strong intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs.
منابع مشابه
(E)-4-Bromo-2-[(4-ethylphenyl)iminomethyl]phenol
In the title compound, C(15)H(14)BrNO, the dihedral angle between the two benzene rings is 43.99 (2)°. The mol-ecular conformation is influenced by an intra-molecular O-H⋯N hydrogen bond.
متن کامل(E)-2-[(3-Fluorophenyl)iminomethyl]-4-(trifluoromethoxy)phenol
The title compound, C(14)H(9)F(4)NO(2), is a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The H atom is located on the hydr-oxy O atom rather than on the N atom. This H atom is involved in a strong intra-molecular O-H⋯N hydrogen bond. The mol-ecule is almost planar, the angle between the benzene rings being 2.14 (13)°.
متن کامل1-{(E)-[4-Bromo-2-(trifluoromethoxy)phenyl]iminomethyl}naphthalen-2-ol
The title compound, C18H11BrF3NO2, crystallizes in the phenol-imine tautomeric form, with a strong intra-molecular O-H⋯N hydrogen bond. The dihedral angle between the naphthalene ring system and the benzene ring is 28.54 (10)°.
متن کامل4-Bromo-2-[(E)-(4-chlorophenyl)iminomethyl]phenol
In the title compound, C(13)H(9)BrClNO, the dihedral angle between the substituted benzene rings is 43.90 (11)°. Strong intra-molecular O-H⋯N hydrogen bonds generate S(6) ring motifs. The crystal structure features short intemolecular Br⋯Br [3.554 (2) Å] and Cl⋯Cl [3.412 (2) Å] contacts. The crystal packing is further stabilized by inter-molecular C-H⋯O and C-H⋯π inter-actions.
متن کاملBis{6-bromo-4-chloro-2-[(E)-(2-chlorophenyl)iminomethyl]phenolato-κ2 N,O}copper(II)
In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL(2) {where HL= 2-[(E)-(2-chloro-phenyl-imino)-meth-yl]-6-bromo-4-chloro-phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol-ecules are linked via Cu⋯Cl inter-actions [2.9933 (11) Å], forming a two-dimensional network parallel to the bc plane. They are also Cl⋯Cl int...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011